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Chemical Oxygen Demand Calculator

Chemical Oxygen Demand Calculator

Calculate COD for water quality assessment and wastewater treatment monitoring

Calculate Chemical Oxygen Demand

Volume of ferrous ammonium sulfate for blank run

Volume of ferrous ammonium sulfate for sample

Normality of ferrous ammonium sulfate solution

Volume of original water sample tested

COD Analysis Results

0.0
COD (mg/L)
Excellent
Water Quality
0.0
mg/L
0.0
ppm
0.000
g/L
0.0
Est. BOD (mg/L)

Formula: COD = (A - B) × N × 8000 / Sample Volume

Calculation: COD = (0 - 0) × 0 × 8000 / 0 = 0.0 mg/L

Assessment: Very clean water with minimal organic pollution

Typical Applications:

  • Drinking water
  • Aquaculture
  • Swimming

Example Calculation

Municipal Wastewater Sample

FAS Blank Volume (A): 30.0 mL

FAS Sample Volume (B): 12.9 mL

FAS Normality (N): 0.25 N

Sample Volume: 50.0 mL

Calculation Steps

COD = (A - B) × N × 8000 / Sample Volume

COD = (30.0 - 12.9) × 0.25 × 8000 / 50.0

COD = 17.1 × 0.25 × 8000 / 50.0

COD = 34,200 / 50.0

COD = 684 mg/L

Typical COD Values by Water Type

Drinking Water

Range: < 10 mg/L

Treated municipal water

Surface Water

Range: 5-25 mg/L

Rivers, lakes (unpolluted)

Groundwater

Range: 2-10 mg/L

Wells, springs

Swimming Pool

Range: 2-5 mg/L

Chlorinated pool water

Municipal Wastewater

Range: 200-600 mg/L

Before treatment

Industrial Wastewater

Range: 500-5000 mg/L

Food processing, chemicals

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COD Quality Standards

Drinking Water

≤ 20 mg/L

WHO standard

Surface Water

5-25 mg/L

Clean rivers/lakes

Discharge Limit

≤ 125 mg/L

EU urban wastewater

Raw Sewage

200-800 mg/L

Before treatment

COD Formula

Basic Formula
COD = (A - B) × N × 8000 / V
Variables

A = FAS blank volume (mL)

B = FAS sample volume (mL)

N = FAS normality

V = Sample volume (mL)

Constants

8000 = Oxygen equivalent

(mg O₂/meq)

COD vs BOD

COD (Chemical)
Chemical oxidation
2-3 hours test
Higher values
BOD (Biological)
Microbial oxidation
5 days test
Lower values
Typical Ratio
BOD/COD = 0.3-0.8
Municipal: ~0.5

Understanding Chemical Oxygen Demand

What is COD?

Chemical Oxygen Demand (COD) measures the amount of oxygen required to chemically oxidize organic matter in water. It's a critical parameter for assessing water quality and the effectiveness of wastewater treatment processes.

Key Applications

  • Water quality monitoring and assessment
  • Wastewater treatment efficiency evaluation
  • Industrial discharge compliance monitoring
  • Environmental impact assessment

Environmental Significance

High COD levels indicate organic pollution that can deplete dissolved oxygen in water bodies, threatening aquatic life and ecosystem health. COD testing is essential for protecting water resources and ensuring environmental sustainability.

COD Test Procedure

COD = (A - B) × N × 8000 / Sample Volume

Result in mg/L (ppm)

Test Steps

  1. 1. Sample Preparation: Collect representative water sample
  2. 2. Digestion: Heat sample with K₂Cr₂O₇ and H₂SO₄
  3. 3. Cooling: Allow digested sample to cool
  4. 4. Titration: Titrate with FAS solution
  5. 5. Calculation: Apply COD formula

Note: COD tests use strong oxidizing agents and should be performed in properly equipped laboratories following safety protocols.

Applications and Standards

Drinking Water

WHO recommends COD ≤ 20 mg/L for safe drinking water. Lower values indicate minimal organic contamination.

Wastewater Treatment

Monitor treatment efficiency by comparing influent and effluent COD levels. Typical removal: 80-95%.

Industrial Monitoring

Ensure compliance with discharge limits and assess impact of industrial processes on water quality.

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