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Heat of Combustion Calculator

Heat of Combustion Calculator

Calculate the higher heating value (HHV) for fuel combustion reactions

Calculate Heat of Combustion

Energy released without considering water vapor condensation

MJ/kg

Standard value for water is 2.257 MJ/kg at 25°C

Number of water molecules produced in combustion

Amount of fuel that undergoes combustion

Combustion Results

0.00
MJ/kg
Heat of Combustion (HHV)
0.000
Water Vaporization Energy (MJ/kg)
0.0%
Efficiency vs LHV
0.00
H₂O/Fuel Ratio

Formula: Hc = LHV + (Hv × nH₂O/nfuel)

Calculation: 0.00 + (2.257 × 0/1) = 0.00 MJ/kg

Description: Higher heating value includes energy from water vapor condensation

Example Combustion Reactions

Methane Combustion

CH₄ + 2O₂ → CO₂ + 2H₂O

Complete combustion of methane produces 2 moles of water per mole of fuel

LHV = 50 MJ/kg, H₂O = 2 mol, Fuel = 1 mol

Ethanol Combustion

C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O

Ethanol combustion produces 3 moles of water per mole of fuel

LHV = 26.8 MJ/kg, H₂O = 3 mol, Fuel = 1 mol

Propane Combustion

C₃H₈ + 5O₂ → 3CO₂ + 4H₂O

Propane combustion produces 4 moles of water per mole of fuel

LHV = 46.4 MJ/kg, H₂O = 4 mol, Fuel = 1 mol
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Energy Values Reference

Heat of Vaporization
Water: 2.257 MJ/kg (25°C)
Energy Units
1 MJ/kg = 1,000 kJ/kg
1 MJ/kg = 429.9 BTU/lb
1 MJ/kg = 238.8 cal/g
HHV vs LHV
HHV includes energy from water vapor condensation

Common Fuels LHV

Methane50 MJ/kg
Ethane47.8 MJ/kg
Propane46.4 MJ/kg
Butane45.8 MJ/kg
Natural Gas48 MJ/kg
Gasoline44 MJ/kg
Diesel43 MJ/kg
Ethanol26.8 MJ/kg
Hydrogen120 MJ/kg
Coal25 MJ/kg
Wood18 MJ/kg

Combustion Types

Complete Combustion
Fuel + O₂ → CO₂ + H₂O + Energy
Incomplete Combustion
Limited oxygen produces CO and less energy
Stoichiometric
Exact fuel-to-oxygen ratio for complete reaction

Understanding Heat of Combustion

What is Heat of Combustion?

Heat of combustion (also called higher heating value or HHV) is the amount of energy released when a fuel undergoes complete combustion with oxygen. It includes the energy recovered from condensing the water vapor produced during combustion.

Key Components

  • Lower Heating Value (LHV): Energy without water vapor condensation
  • Heat of Vaporization: Energy required to vaporize water
  • Stoichiometry: Molar ratios of reactants and products

The Combustion Formula

Heat of Combustion

Hc = LHV + (Hv × nH₂O/nfuel)

Hc = Heat of combustion (higher heating value)

LHV = Lower heating value

Hv = Heat of vaporization of water

nH₂O = Moles of water produced

nfuel = Moles of fuel combusted

General Combustion

CxHy + O₂ → xCO₂ + (y/2)H₂O

Hydrocarbon fuel combustion with oxygen

Applications and Importance

Energy Production

Power plants and heating systems use HHV to calculate energy output and efficiency.

Fuel Comparison

Compare different fuels based on their energy content per unit mass or volume.

Engine Design

Automotive and aerospace engineers use HHV for engine performance calculations.

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