Calorimetry Calculator

Calculate heat transfer, temperature changes, and energy exchange in thermal systems

Calorimetry Analysis

Object 1

Object 2

Heat Exchange Results

23.48°C
Equilibrium Temperature
0.0
Total Heat Transfer (kJ)
Energy Conserved

Object 1 Heat Change

14.54 kJ
Heat Gained

Object 2 Heat Change

-14.54 kJ
Heat Lost

Common Substances

Water

c = 4.18 kJ/kg·K

H = 334 kJ/kg

Ice

c = 2.05 kJ/kg·K

H = 334 kJ/kg

Aluminum

c = 0.9 kJ/kg·K

Copper

c = 0.38 kJ/kg·K

Iron

c = 0.45 kJ/kg·K

Silver

c = 0.24 kJ/kg·K

Gold

c = 0.13 kJ/kg·K

Lead

c = 0.13 kJ/kg·K

Mercury

c = 0.14 kJ/kg·K

Glass

c = 0.84 kJ/kg·K

Calorimetry Formulas

Heat Change

Q = m × c × ΔT

Sensible heat transfer

Phase Change

Q = m × H

Latent heat transfer

Energy Conservation

ΣQ = 0

Total heat change is zero

Enthalpy Change

ΔH = (M × Q) / m

Chemical reaction enthalpy

Understanding Calorimetry

What is Calorimetry?

Calorimetry is the science of measuring heat transfer during chemical reactions, phase transitions, or temperature changes. It's based on the law of conservation of energy, which states that energy cannot be created or destroyed in an isolated system.

Types of Heat Transfer

  • Sensible Heat: Heat that causes temperature change
  • Latent Heat: Heat absorbed or released during phase changes
  • Reaction Heat: Heat involved in chemical reactions

Key Principles

Energy Conservation: Q₁ + Q₂ + Q₃ + ... = 0

Heat Equation: Q = mcΔT

Phase Change: Q = mH

Temperature Change: ΔT = T_final - T_initial

Applications

  • Material Analysis: Determining specific heat capacities
  • Chemical Reactions: Measuring enthalpy changes
  • Phase Studies: Analyzing melting and boiling points
  • Quality Control: Testing material properties

Problem Solving Steps

Heat Exchange Problems

  1. 1. Identify all objects and their properties
  2. 2. Write heat equation for each object
  3. 3. Apply conservation of energy
  4. 4. Solve for the unknown variable
  5. 5. Check that energy is conserved

Example:

Mix 0.5 kg copper (100°C) with 1.0 kg water (20°C). Find the final temperature.

Solution: T_final = (m₁c₁T₁ + m₂c₂T₂) / (m₁c₁ + m₂c₂)

Chemical Reaction Analysis

  1. 1. Measure solution temperature change
  2. 2. Calculate heat absorbed by solution
  3. 3. Determine reaction heat (opposite sign)
  4. 4. Calculate enthalpy per mole
  5. 5. Classify as exo- or endothermic

Coffee-Cup Calorimeter:

Measures enthalpy changes in solution reactions at constant pressure.

ΔH = (Molar Mass × Q_solution) / mass_substance