Electrical Mobility Calculator

Calculate electrical mobility and diffusion using Einstein-Smoluchowski relation

Einstein-Smoluchowski Relation

Electrical Mobility (μ)

Temperature (T)

Charge (q)

Results

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Material Examples

Copper (electrons)

Mobility:
3000 mm²/(V⋅s)
Charge:
-1e
At 20°C, D =
75.785 mm²/s
Electrons in copper wire at room temperature

Silicon (electrons)

Mobility:
1350 mm²/(V⋅s)
Charge:
-1e
At 20°C, D =
34.103 mm²/s
Electrons in pure silicon at room temperature

Na⁺ in water

Mobility:
0.0519 mm²/(V⋅s)
Charge:
+1e
At 20°C, D =
0.001 mm²/s
Sodium ions in aqueous solution

Key Concepts

Electrical Mobility

Velocity per unit electric field

Diffusion Constant

Rate of spreading in thermal motion

Drift Velocity

Average velocity in electric field

Charge Carriers

Electrons, holes, or ions

Physical Constants

Boltzmann Constant

kB = 1.381 × 10⁻²³ J/K

Elementary Charge

e = 1.602 × 10⁻¹⁹ C

Room Temperature

T = 293.15 K (20°C)

Understanding Electrical Mobility

What is Electrical Mobility?

Electrical mobility (μ) is a fundamental property that describes how quickly charge carriers (electrons, holes, or ions) move through a material when subjected to an electric field. It's defined as the drift velocity per unit electric field strength.

Einstein-Smoluchowski Relation

This fundamental relation connects the random thermal motion of particles (characterized by the diffusion constant D) to their response to external electric fields (characterized by electrical mobility μ).

Physical Interpretation

Diffusion Constant (D):

Measures how fast particles spread due to thermal motion

Mobility (μ):

Measures how fast particles move in an electric field

Temperature (T):

Higher temperature increases both diffusion and thermal energy

Applications and Examples

Semiconductors

  • • Silicon: electron mobility ≈ 1350 mm²/(V⋅s)
  • • Germanium: electron mobility ≈ 3900 mm²/(V⋅s)
  • • GaAs: electron mobility ≈ 8500 mm²/(V⋅s)
  • • Temperature dependence: μ ∝ T⁻³/²

Electrolytes

  • • Na⁺ in water: ≈ 0.052 mm²/(V⋅s)
  • • Cl⁻ in water: ≈ 0.079 mm²/(V⋅s)
  • • H⁺ in water: ≈ 0.363 mm²/(V⋅s)
  • • Depends on ion size and hydration

Mathematical Relationships

Einstein Relation

D = μ kB T / |q|

Drift Velocity

vd = μ E

Conductivity

σ = n q μ