Root Mean Square Speed Calculator for Ideal Gas

Calculate RMS speed, kinetic energy, and molecular velocities for ideal gases using kinetic theory

Calculate RMS Speed for Ideal Gas

Select a common gas or choose custom to enter your own molar mass

Temperature of the gas

J/(K·mol)

Universal gas constant (default: 8.314 J/(K·mol))

RMS Speed Results

502.43 m/s
RMS Speed (v_rms)
6.071 zJ
Avg Kinetic Energy
462.90 m/s
Average Speed (v_avg)
410.23 m/s
Most Probable Speed (v_mp)

Gas: Air (dry)

Formula used: v_rms = √(3RT/M)

Temperature: 293.15 K

Molar mass: 28.965 g/mol

Speed Comparison

v_rms : v_avg : v_mp1.225 : 1.128 : 1.000
Ratio (v_rms/v_mp)1.225

Physical Interpretation

✅ RMS speed represents the square root of the mean square velocity
🌡️ Higher temperature = higher molecular speeds
⚖️ Lighter gases move faster than heavier gases at same temperature

Example Calculations

Air at Room Temperature

Gas: Air (dry)

Temperature: 20°C = 293.15 K

Molar mass: 28.965 g/mol = 0.028965 kg/mol

RMS speed: v_rms = √(3 × 8.314 × 293.15 / 0.028965) ≈ 502 m/s

Hydrogen at Standard Temperature

Gas: Hydrogen (H₂)

Temperature: 273.15 K (0°C)

Molar mass: 2.016 g/mol = 0.002016 kg/mol

RMS speed: v_rms = √(3 × 8.314 × 273.15 / 0.002016) ≈ 1838 m/s

Common Gas Properties

GasMolar Mass
Hydrogen2.016 g/mol
Helium4.003 g/mol
Nitrogen28.014 g/mol
Air28.965 g/mol
Oxygen31.998 g/mol
Argon39.948 g/mol
Carbon Dioxide44.009 g/mol
Methane16.043 g/mol

Speed Relationships

RMS Speed

v_rms = √(3RT/M)

Root mean square velocity

Average Speed

v_avg = √(8RT/πM)

Mean molecular speed

Most Probable Speed

v_mp = √(2RT/M)

Peak of distribution

Physical Constants

Gas constant (R)8.314 J/(K·mol)
Boltzmann (k)1.381×10⁻²³ J/K
Avogadro (Nₐ)6.022×10²³ mol⁻¹
STP Temperature273.15 K
Room Temperature293.15 K

Understanding Root Mean Square Speed

What is RMS Speed?

Root Mean Square (RMS) speed is a measure of the average speed of gas molecules. It represents the square root of the mean of the squares of individual molecular velocities. RMS speed is particularly useful because it relates directly to the kinetic energy of gas molecules.

Kinetic Theory Assumptions

  • Gas molecules are point particles with negligible volume
  • Collisions are perfectly elastic
  • No intermolecular forces except during collisions
  • Molecules are in constant, random motion

Mathematical Derivation

Starting from Ideal Gas Law

PV = nRT

Combined with kinetic energy: KE = ½mv² = (3/2)kT

RMS Speed Formula

v_rms = √(3RT/M)

Where R = gas constant, T = temperature, M = molar mass

Note: RMS speed increases with temperature and decreases with molar mass.

Applications and Significance

Diffusion and Effusion

RMS speed determines how quickly gases diffuse and effuse. Lighter gases like hydrogen diffuse faster than heavier gases.

Atmospheric Escape

Molecules with speeds exceeding escape velocity can leave planetary atmospheres, explaining atmospheric composition.

Chemical Kinetics

Reaction rates depend on molecular speeds and collision frequency, which are related to RMS speed.

Speed Distribution

Maxwell-Boltzmann Distribution

Gas molecules follow a Maxwell-Boltzmann speed distribution. The three characteristic speeds are:

  • • Most probable speed (peak of curve)
  • • Average speed (mean of distribution)
  • • RMS speed (related to kinetic energy)

Temperature Effects

As temperature increases, the distribution curve flattens and shifts to higher speeds. All three characteristic speeds increase proportionally to the square root of temperature.