Rydberg Equation Calculator

Calculate hydrogen emission spectrum wavelengths and frequencies using the Rydberg formula for atomic spectroscopy

Calculate Hydrogen Spectral Lines

Hydrogen-like atoms only

Must be greater than final state

Lower energy level (ground state = 1)

Spectral Line Results

🌈Balmer Series

Visible spectrum region

656.11
Wavelength (nm)
456.922
Frequency (THz)
1.890
Energy (eV)
15241
Wavenumber (cm⁻¹)

Transition Details

Atom: Hydrogen (H)

Transition: n=3 → n=2

Energy Change: ΔE = 1.890 eV

Physical Properties

Wavelength (m): 6.561e-7

Frequency (Hz): 4.569e+14

Energy (J): 3.028e-19

Rydberg Equation: 1/λ = R·Z²·(1/n₁² - 1/n₂²) = 1.524 × 10⁶ m⁻¹

Rydberg Constant: R = 1.0974e+7 m⁻¹

Example Calculation

Balmer Series: n=4 → n=2 (Hydrogen)

Transition: Fourth to second energy level

Calculation: 1/λ = R·1²·(1/2² - 1/4²) = 1.097×10⁷·(1/4 - 1/16)

Result: 1/λ = 1.097×10⁷·(0.25 - 0.0625) = 2.056×10⁶ m⁻¹

Wavelength: λ = 486 nm (Blue-green light)

Series: Balmer series (visible spectrum)

Lyman Series: n=2 → n=1 (Hydrogen)

Transition: Second to ground state

Calculation: 1/λ = R·1²·(1/1² - 1/2²) = 1.097×10⁷·(3/4)

Wavelength: λ = 122 nm (Ultraviolet)

Energy: 10.2 eV (Lyman alpha line)

Hydrogen Spectral Series

Lyman Series

n → 1

Ultraviolet
Balmer Series

n → 2

Visible
Paschen Series

n → 3

Infrared
Brackett Series

n → 4

Infrared
Pfund Series

n → 5

Infrared
Humphreys Series

n → 6

Infrared

Physics Constants

Rydberg constant (R)1.097 × 10⁷ m⁻¹
Speed of light (c)2.998 × 10⁸ m/s
Planck constant (h)6.626 × 10⁻³⁴ J⋅s
Electron charge (e)1.602 × 10⁻¹⁹ C

Famous Spectral Lines

Lyman α (n=2→1)121.6 nm
Balmer α (n=3→2)656.3 nm
Balmer β (n=4→2)486.1 nm
Balmer γ (n=5→2)434.0 nm
Paschen α (n=4→3)1875 nm

Understanding the Rydberg Equation

What is the Rydberg Equation?

The Rydberg equation is a mathematical formula used to predict the wavelengths of spectral lines in hydrogen and hydrogen-like atoms. It was developed by Johannes Rydberg in 1888 and provides a precise way to calculate the electromagnetic radiation emitted during electron transitions.

Key Principles

  • Electrons exist only in specific energy levels
  • Energy is emitted when electrons drop to lower levels
  • Each transition produces a specific wavelength
  • Different series correspond to different final states

Rydberg Formula

1/λ = R·Z²·(1/n₁² - 1/n₂²)

  • λ: Wavelength of emitted light
  • R: Rydberg constant (1.097 × 10⁷ m⁻¹)
  • Z: Atomic number (1 for hydrogen)
  • n₁: Lower energy level (final state)
  • n₂: Higher energy level (initial state)

Note: The equation is most accurate for hydrogen and hydrogen-like ions with only one electron.

Applications in Science

Atomic Spectroscopy

Identify elements in stars, gases, and laboratory samples by analyzing their characteristic spectral lines and emission patterns.

Quantum Mechanics

Fundamental evidence for quantized energy levels in atoms, supporting Bohr's model and modern quantum mechanical theory.

Astronomy

Determine composition, temperature, and motion of celestial objects through analysis of hydrogen absorption and emission lines.